"Rotaxanes" Natural Recordings by Native Speakers
Rotaxanes are a type of mechanically interlocked molecular architecture. In a rotaxane, a linear molecule (the axle) is threaded through a molecular ring (the wheel), and the two components are mechanically bonded together through covalent bonds.
Imagine a mechanical embodiment of a sliding door: the axle is like the door's rod, and the wheel is like the door. However, unlike a sliding door, the axle cannot be removed from the wheel in the case of a rotaxane.
Rotaxanes have unique properties due to their mechanical bonding:
1. Stability: The mechanical bonding between the wheel and the axle provides additional stability to the molecule.
2. ヘSelective binding: The wheel-axle interaction can be selective, allowing the molecular system to bind specifically to certain targets.
3. Switching behavior: Rotaxanes can exhibit switching behavior by moving the wheel along the axle in response to external stimuli, such as changes in temperature, pH, or the presence of specific molecules.
Rotaxanes have various applications in fields like:
1. Supramolecular chemistry: Studying the interplay between the wheel and axle components provides insights into molecular recognition, binding selectivity, and energy transfer.
2. Molecular machines: Rotaxanes can be designed to perform tasks such as switching, oscillating, or pumping, which can lead to innovative self-assembly and nanoscale device applications.
3. Biomimetics: Rotaxane-based systems can be used to model biological processes, such as protein function, folding, and interactions.
4. Materials science: Rotaxanes can be utilized in the development of shape-memory materials, switchable metamaterials, and self-healing composites.
Overall, the interlocked architecture of rotaxanes enables sophisticated control and manipulation of molecular interactions, leading to a wide range of interesting properties and applications.
Rotationplasty is a surgical procedure where a portion of a limb is rotated 180-degrees and reattached, often performed on children who have had the lower part of their limb severely damaged, usually due to tumor removal or severe injuries.<br><br>The goal of this surgery is to create a functional "knee" that can dance or bear weight.
Rotations refer to the act of turning or revolving around a central point, often repeatedly. In different contexts, it can have various meanings, such as:<br><br>1. In physics and mathematics, a rotation is the movement of an object around a fixed point or axis, which can be a 180-degree rotation, 360-degree rotation, or a fraction of a rotation.<br><br>2. In sports, a rotation can refer to the series of players who take part in a specific position or task, often in a sequence, such as a batting rotation in baseball or a rotating door in tennis.<br><br>3. In chemistry, a rotation can refer to the arrangement or structure of molecules in a crystal lattice, such as a chiral rotation or a rotational motion.<br><br>4. In medical and industrial settings, rotation can refer to the act of changing the position of a machine or instrument, such as a rotating part in a machine.<br><br>5. In educational or academic settings, rotation can refer to the act of exchanging or replacing one thing with another, such as a class or group rotation in team-building exercises.<br><br>6. In movement or dance, rotation can refer to a movement of one's body around a central axis, often recurring or repeating.<br><br>7. In business or politics, rotation can refer to the process of replacing or exchanging one thing for another, such as a government or executive rotation.<br><br>8. In medical terminology, a rotation can refer to a twenties rotation of the body, or rotating part of something, or of an organ.
Rotative refers to something that rotates or refers to rotation. It can describe a machine or device that rotates, or a movement that involves rotation.<br><br>Example: "The rotative engine powered the pump."
A device or mechanism that rotates or causes something to rotate, often used to change the direction or position of something. It can also refer to a muscle that rotates a particular part of the body or a movement where the arm or shoulder rotates, such as a rotator cuff in the shoulder.
A virus that causes gastroenteritis, an inflammation of the stomach and intestines. It is the most common cause of severe diarrhea in children worldwide and often leads to dehydration.
A rotaxane is a type of molecular architecture in organic chemistry. It consists of a macrocycle ('ring') that encircles a dumbbell-shaped component (axis), which contains two terminal groups. The macrocycle is mechanically bound to the axis by two end groups (á stators) through a process called coordination bonding.<br><br>Rotaxanes can be viewed as a combination of a macrocycle and a dumbbell-shaped molecule linked together. The macroring encircles the axis in a specific orientation and is held together by weak chemical bonds (e.g. dipole-dipole forces, van der Waals forces), which can be too weak to separate the component, hence the term "mechanochemical" is not used for molecules that sustain such bonds between their constituent parts.<br><br>Rotaxanes can be considered as a type of molecule that consists of three parts described as a macrocycle and two ends in which two of its non-covalent closures of the dumbbell-shaped axis.
The Junior Reserve Officers' Training Corps (JROTC) is a leadership and citizenship program for high school students. It's a covers both civics and first aid, and focuses on teaching students skills such as leadership, teamwork, and community service.
A memorized verbal routine or set of actions performed without much thought or creativity, often in a mechanical or automatic way: the secretary's workdays were a series of routine tasks; her life on the farm was a routine of hard work and rest.
Rotella is a brand of automotive oil, but the word can also refer to a European surname, specifically Italian and Greek.
Rotenone is a naturally occurring chemical insecticide derived from the roots of certain plants, such as the Derris tree. It is a non-selective insecticide that works by inhibiting the energy-producing process in cells, killing insects and other organisms by suffocation. Rotenone is used to control insect pests, particularly in agriculture and in aquariums. It is also used in some fisheries to remove insects and other unwanted organisms from the water.
Rothera Island, also known as Rothera, is a small Antarctic island lying south of Adelaide Island, in the Errera Channel, which connects it to the Antarctic mainland in Graham Land, Antarctica.